EN 10095 Specification for heat resisting steel and nickel alloys.

This Standard Specification covers the grades of wrought steels and nickel alloys listed in Tables below which are usually employed for products, for which the main requirement is their resistance to the effects of hot gases and products of combustion at temperatures above 550 8C.
EN 10095 specifies the technical delivery conditions for semi-finished products, for hot or cold rolled sheet/plate and strip, hot or cold formed bars, rods and sections of heat resisting steels and nickel alloys.
Materials covered in this European Standard are classified according to their structure into:
- ferritic steels.
- austenitic-ferritic steels.
- austenitic steels.
- austenitic nickel alloys.

Chemical composition (cast analysis)1) of ferritic heat-resisting steels

Steel designation % by mass
Name Number C Si Mn
max.
P
max.
S
max.
Cr A1 Others
X10CrAlSi7 1.4713 max. 0.12 0.50 to 1.00 1.00 0.040 0.015 6.00 to 8.00 0.50 to 1.00
X10CrAlSi13 1.4724 max. 0.12 0.70 to 1.40 1.00 0.040 0.015 12.00 to 14.00 0.70 to 1.20
X10CrAlSi18 1.4742 max. 0.12 0.70 to 1.40 1.00 0.040 0.015 17.00 to 19.00 0.70 to 1.20
X10CrAlSi25 1.4762 max. 0.12 0.70 to 1.40 1.00 0.040 0.015 23.00 to 26.00 1.20 to 1.70
X18CrN28 1.4749 0.15 to 0.20 max. 1.00 1.00 0.040 0.015 26.00 to 29.00 -- N: 0.15 to 0.25
X3CrAlTi18-2 1.4736 max. 0.04 max. 1.00 1.00 0.040 0.015 17.00 to 18.00 1.70 to 2.10 0.2 + 4(C + N) ≤ Ti ≤ 0.80

Chemical composition (cast analysis)1) of austenitic-ferritic and austenitic heat-resisting steels

Steel designation % by mass
Name Number C Si Mn P
max.
S
max.
Cr Ni N Others
Austenitic heat-resisting steels
X8CrNiTi18-10 1.4878 max. 0.10 max. 1.00 max. 2.00 0.045 0.015 17.00 to 19.00 9.00 to 12.00 Ti: 5 X % C ≤ Ti ≤ 0.80
X15CrNisi20-12 1.4828 max. 0.20 1.50 to 2.50 max. 2.00 0.045 0.015 19.00 to 21.00 11.00 to 13.00 max. 0.11
X9CrNiSiNCe21-11-2 1.4835 0.05 to 0.12 1.40 to 2.50 max. 1.00 0.045 0.015 20.00 to 22.00 10.00 to 12.00 0.12 to 0.20 Ce: 0.03 to 0.08
X12CrNi23-13 1.4833 max. 0.15 max. 1.00 max. 2.00 0.045 0.015 22.00 to 24.00 12.00 to 14.00 max. 0.11
X8CrNi25-21 1.4845 max. 0.10 max. 1.50 max. 2.00 0.045 0.015 24.00 to 26.00 19.00 to 22.00 max. 0.11
X15CrNiSi25-21 1.4841 max. 0.20 1.50 to 2.50 max. 2.00 0.045 0.015 24.00 to 26.00 19.00 to 22.00 max. 0.11
X12NiCrSi35-16 1.4864 max. 0.15 1.00 to 2.00 max. 2.00 0.045 0.015 15.00 to 17.00 33.00 to 37.00 max. 0.11
X10NiCrAlTi32-21 1.4876 max. 0.12 max. 1.00 max. 2.00 0.030 0.015 19.00 to 23.00 30.00 to 34.00 A1: 0.15 to 0.60
Ti: 0.15 to 0.60
X6NiCrNbCe32-27 1.4877 0.04 to 0.08 max. 0.30 max. 1.00 0.020 0.010 26.00 to 28.00 31.00 to 33.00 max. 0.11 A1: max. 0.025
Ce : 0.05 to 0.10
Nb:0.60 to 1.00
X25CrMnNiN25-9-7 1.4872 0.20 to 0.30 max. 1.00 8.00 to 10.00 0.045 0.015 24.00 to 26.00 6.00 to 8.00 0.20 to 0.40
X6CrNiSiNCe19-10 1.4812 0.04 to 0.08 1.00 to 2.00 max. 1.00 0.045 0.015 18.00 to 20.00 9.00 to 11.00 0.12 to 0.20 Ce: 0.03 to 0.08
X6NiCrSiNCe35-25*) 1.4854 0.04 to 0.08 1.20 to 2.00 max. 2.00 0.040 0.015 24.00 to 26.00 34.00 to 36.00 0.12 to 0.20 Ce: 0.03 to 0.08
X10NiCrSi35-19 1.4886 max. 0.15 1.00 to 2.00 max. 2.00 0.030 0.015 17.00 to 20.00 33.00 to 37.00 max. 0.11
X10NiCrSiNb35-22 1.4887 max. 0.15 1.00 to 2.00 max. 2.00 0.030 0.015 20.00 to 23.00 33.00 to 37.00 max. 0.11 Nb: 1.00 to 1.50
Austenitic-ferritic heat-resisting steel
X15CrNiSi25-4 1.4887 0.10 to 0.20 0.8 to 1.50 max. 2.00 0.040 0.015 24.50 to 26.50 3.50 to 5.50 max. 0.11

Chemical composition (cast analysis)1) of austenitic nickel alloys

Alloys designation % by mass
Name Number C Mn
max
Si
max
P
max.
S
max.
Ni Cr Co Fe Mo A1 Ti Cu
max.
Nb + Ta B
max.
Ce
NiCr15Fe 2.4816 0.05 to 0.10 1.00 0.50 0.020 0.015 min. 72.00 14.00 to 17.00 2) 6.00 to 10.00 max. 0.30 max. 0.30 0.50
NiCr20Ti 2.4851 0.08 to 0.15 1.00 1.00 0.020 0.015 Rest 18.00 to 21.00 max. 5.00 max. 5.00 max. 0.30 0.20 to 0.60 0.50
NiCr22Mo9Nb 2.4856 0.03 to 0.10 0.50 0.50 0.020 0.015 min. 58.00 20.00 to 23.00 max. 1.00 max. 5.00 8.00 to 10.00 max. 0.40 max. 0.40 0.50 3.15 to 4.15
NiCr23Fe 2.4851 0.03 to 0.10 1.00 0.50 0.020 58.00 to 63.00 min. 58.00 21.00 to 25.00 2) max. 18.00 1.00 to 1.70 max. 0.50 0.50 0.006
NiCr28FeSiCe 2.4889 0.05 to 0.12 1.00 2.50 to 3.00 0.020 0.010 min. 45.00 26.00 to 29.00 2) 21.00 to 25.00 0.30 0.03 to 0.09

1)Elements not listed in the table may not be intentionally added to the alloy without the agreement of the purchaser except for finishing the cast. All appropriate precautions are to be taken to avoid addition of such elements from scrap and other materials used in production which would impair mechanical properties and the suitability of the alloy.

2) A maximum of 1,5 % Co is allowed and counted as nickel. Reporting of cobalt is not required.

*) Patented steel grade.

Mechanical Properties

Designation Products Heat
treatment
conditions
HB max.
1) 2) 3)
Proof strength Tensile strength A % min.
Name Number Form Thickness 𝘢
or diameter
𝘥 mm
Rp0.2
N/mm2
Rp1.0
N/mm2
Rm
N/mm2
Long products Flat products
min 3) min 3) 1) 3) 0.5 ≤ a ≤ 3
1, tr
3 < a
1 tr
Ferritic heat resisting steels
X10CrAlSi7 1.4713 flat products a ≤ 12 +A 192 220 420 to 620 20 -- 20 15
X10CrAlSi13 1.4724 +A 192 250 450 to 650 15 13 15 15
X10CrAlSi18 1.4742 bars d ≤ 25 +A 212 270 500 to 700 15 13 15 15
X10CrAlSi25 1.4762 +A 223 280 520 to 720 10 13 15 15
X18CrN28 1.4749 rods and sections d ≤ 25 +A 212 280 500 to 700 15 13 15 15
X3CrAlTi18-2 1.4736 +A 200 280 500 to 650 -- 25 25 25
Austenitic heat resisting steels
X8CrNiTi18-10 1.4878 flat products a ≤ 75 +A 215 190 230 500 to 720 401) 40 40
X15CrNiSi20-12 1.4828 +A 223 230 270 550 to 750 301) 40 40
X9CrNiSiNCe21-11-2 1.4835 +A 210 310 350 650 to 850 401) 37 40
X12CrNi23-13 1.4833 +A 192 210 250 500 to 700 351) 33 35
X8CrNi25-21 1.4845 bars d ≤ 160 +A 192 210 250 500 to 700 351) 33 35
X15CrNiSi25-21 1.4841 +A 223 230 270 550 to 750 301) 28 30
X12NiCrSi35-16 1.4864 +A 223 230 270 550 to 750 301) 28 30
X10NiCrAlTi32-21 1.4876 +A 192 170 210 450 to 680 301) 28 30
X6NiCrNbCe32-27 1.4877 +A 223 180 220 500 to 750 351) -- --
X25CrMnNiN25-9-7 1.4872 rods and
sections
a ≤ 72 +A 311 500 540 850 to 1050 251) -- --
X6CrNiSiNCe19-10 1.4818 +A 210 290 330 600 to 800 401) 30 40
X6NiCrSiNCe35-25 1.4854 +A 210 300 340 650 to 850 401) 40 40
X10NiCrSi35-19 1.4886 +A 200 270 300 500 to 650 40 -- --
X10NiCrSiNb35-22 1.4887 +A 200 270 300 500 to 650 40 -- --
Austenitic-ferritic heat resisting steel
X15CrNiSi25-4 1.4821 flat products a ≤ 12 +AT 225 400 -- 600 to 850 16 --- 16 12
bars d ≤ 60
rods d ≤ 25
Heat resisting nickel alloys
NiCr15Fe 2.4816 flat products a ≤ 75 +AT 200 240 -- 550 to 850 30 30 30 --
bars d ≤ 160
rods d ≤ 25
NiCr20Ti 2.4951 flat products a ≤ 75 +AT 230 240 -- 650 to 850 30 -- 30 --
bars d ≤ 160
rods d ≤ 25
NiCr22Mo9Nb 2.4856 flat products 3 ≤ a < 75 +AT 240 380 -- 760 to 100 -- -- 30 30
a < 3 415 -- 820 to 1050 -- 30 -- --
bars 100 < d ≤ 250 345 - 760 to 1000 25 -- -- --
d ≤ 100 415 -- 820 to 1050 30 -- -- --
rods d ≤ 25 415 - 820 to 1050 30 -- -- --
NiCr23Fe 2.4851 flat products a ≤ 75 +AT 220 205 -- 550 to 750 30 -- 30 30
bars d ≤ 160
rods d ≤ 25
NiCr28FeSiCe 2.4889 flat products a ≤ 50 +AT 220 240 -- 620 to 820 35 35 35 35
bars d ≤ 160

1) The maximum HB values may be raised by 100 units or the maximum tensile strength value may be raised by 200 N/mm2 and the minimum elongation value be lowered to 20 % for sections and bars of ≤ 35 mm thickness having a final cold deformation.

2) For guidance only.

3) For rods, only the tensile strength values apply.

Heat Treatments

Designation Heat Treatments
Name Number Symbol1) Temperatures2)
°C
Type of cooling3)
Ferritic heat resisting steels
X10CrAlSi7 1.4713 +A 780 to 840 a, w 4)
X10CrAlSi13 1.4724 +A 800 to 860 a, w 4)
X10CrAlSi18 1.4742 +A 800 to 860 a, w 4)
X10CrAlSi25 1.4762 +A 800 to 860 a, w 4)
X18CrN28 1.4749 +A 800 to 860 a, w 4)
X3CrAlTi18-2 1.4736 +A 870 to 930 a
Austenitic heat resisting steels6)
X8CrNiTi18-10 1.4878 +AT 1 020 to 1 120 W, a5)
X15CrNiSi20-12 1.4828 +AT 1 050 to 1 150 W, a5)
X9CrNiSiNCe21-11-2 1.4835 +AT 1 020 to 1 120 W, a5)
X12CrNi23-13 1.4833 +AT 1 050 to 1 120 W, a5)
X8CrNi25-21 1.4845 +AT 1 050 to 1 120 W, a5)
X15CrNiSi25-21 1.4841 +AT 1 050 to 1 120 W, a5)
X12NiCrSi35-16 1.4864 +AT 1 020 to 1 120 W, a5)
X10NiCrAlTi32-21 1.4876 +AT 1 050 to 1 120 W, a5)
X6NiCrNbCe32-27 1.4877 +AT 1 050 to 1 120 W, a5)
X25CrMnNiN25-9-7 1.4872 +AT 1 050 to 1 120 W, a5)
X6CrNiSiNCe19-10 1.4818 +AT 1 020 to 1 120 W, a5)
X6NiCrSiNCe35-25 1.4854 +AT 1 100 to 1 150 W, a5)
X10NiCrSi35-19 1.4886 +AT 1 050 to 1 150 W, a5)
X10NiCrSiNb35-22 1.4887 +AT 1 050 to 1 150 W, a5)
Austenitic-ferritic heat resisting steel
X15CrNiSi25-4 1.4821 +AT 1 000 to 1 100 W, a5)
Heat resisting nickel alloys
NiCr15Fe 2.4816 +A 950 to 1 000 W, a5)
NiCr20Ti 2.4951 +AT 1 000 to 1 050 W, a5)
NiCr22Mo9Nb 2.4856 +A 950 to 1 000 W, a5)
NiCr23Fe 2.4851 +AT 1 100 to 1 200 W, a5)
NiCr28FeSiCe 2.4889 +AT 1 150 to 1 200 W, a5)

1) A = annealed; AT = solution annealed.

2) If heat treatment is carried out in a continuous furnace, the upper part of the range specified is usually preferred or even exceeded.

3) a = air; w = water.

4) In special cases furnace cooling is also permitted.

5) Cooling sufficiently rapid.

6) Heat treatment is not required in each case since the material will be exposed to high temperature when in operation.

Maximum Application Temperature Ta For Air

Designation Tamax.
°C
Name Number
Ferritic heat resisting steels
X10CrAlSi7 1.4713 8002)
X10CrAlSi13 1.4724 8502)
X10CrAlSi18 1.4742 1 0002)
X10CrAlSi25 1.4762 1 1502)
X18CrN28 1.4749 1 100
X3CrAlTi18-2 1.4736 1 000
Austenitic heat resisting steels
X8CrNiTi18-10 1.4878 8502)
X15CrNiSi20-12 1.4828 1 0002)
X9CrNiSiNCe21-11-2 1.4835 1 150
X12CrNi23-13 1.4833 1 0002)
X8CrNi25-21 1.4845 1 0502)
X15CrNiSi25-21 1.4841 1 1502)
X12NiCrSi35-16 1.4864 1 1002)
X10NiCrAlTi32-21 1.4876 1 1002)
X6NiCrNbCe32-27 1.4877 1 1502)
X25CrMnNiN25-9-7 1.4872 1 1502)
X6CrNiSiNCe19-10 1.4872 1 050
X6NiCrSiNCe35-25 1.4854 1 170
X10NiCrSi35-19 1.4886 1 100
X10NiCrSiNb35-22 1.4887 1 100
Austenitic-ferritic heat resisting steel
X15CrNiSi25-4 1.4821 1 1002)
Heat resisting nickel alloys
NiCr15Fe 2.4816 1 1502)
NiCr20Ti 2.4951 1 150
NiCr22Mo9Nb 2.4856 1 000
NiCr23Fe 2.4851 1 2002)
NiCr28FeSiCe 2.4889 1 200

1) See Creep Properties For 1% Elongation Table.

2) The loss of metal caused by scaling does not exceed 1 g/m2.h at Ta, and does not exceed 2 g/m2 at Ta + 50 °C on average for a period of 120 h with four intermediate coolings.

Creep Properties Estimated average value of the strength for 1% elongation at elevated temperature1)

Designation Heat
treatment
Elongation 1 % in 1000 h Elongation 1 % in 10 000 h Elongation 1 % in 100 000 h
Name Number 500°C 600°C 700°C 800°C 900°C 1000°C 500°C 600°C 700°C 800°C 900°C 1000°C 500°C 600°C 700°C 800°C 900°C 1000°C
Ferritic heat resisting steels
X10CrAlSi7 1.4713
X10CrAlSi13 1.4724
X10CrAlSi18 1.4742 +A 80 27.5 8.5 3.7 1.8 50 17.5 4.7 2.1 1.0
X10CrAlSi25 1.4762
X18CrN28 1.4749
X3CrAlTi18-2 1.4736
Austenitic heat resisting steels
X8CrNiTi18-10 1.4878 +AT 110 45 15 85 30 10
X15CrNiSi20-12 1.4828 +AT 120 50 20 8 80 25 10 4
X9CrNiSiNCe21-11-2 1.4835 +AT 170 66 31 15.5 (8) 126 45 19 10 (5) 80 26 11 6 (3)
X12CrNi23-13 1.4833 +AT 100 40 18 8 70 25 10 5
X8CrNi25-21 1.4845 +AT 100 45 18 10 90 30 10 4
X15CrNiSi25-21 1.4841 +AT 105 50 23 10 3 95 35 10 4
X12NiCrSi35-16 1.4864 +AT 105 50 25 12 80 35 15 5 40 14 4 1.5
X10NiCrAlTi32-21 1.4876 +AT 130 70 30 13 90 40 15 5
X6NiCrNbCe32-27 1.4877 +AT
X25CrMnNiN25-9-7 1.4872 +AT 55 15 4 34 8 2
X6CrNiSiNCe19-10 1.4818 +AT 147 61 25 9 (2.5) 126 42 15 5 (1.7) 80 26 9 3 (1.0)
X6NiCrSiNCe35-25 1.4854 +AT 150 60 26 12.5 6.5 88 34 15 8 4.5 52 21 9.7 5.1 3.0
X10NiCrSi35-19 1.4886 +AT 110 60 26 12 60 35 20 10 (4)
X10NiCrSiNb35-22 1.4887 +AT 110 60 26 12 60 35 20 10 (4)
Austenitic-ferritic heat resisting steel
X15CrNiSi25-4 1.4821 +AT 80 27.5 8.5 3.7 1.8 50 17.5 4.7 2.1 1.0
Heat resisting nickel alloys
NiCr15Fe 2.4816 +A 153 91 43 18 8 126 66 28 12 4
NiCr28FeSiCe 2.4889 +A 25 11.9 5.9 3.1 16 7.2 3.5 1.9

Creep Properties Estimated average value of the strength for rupture at elevated temperature1)

Designation Heat
treatment
Rupture 1 % in 1000 h Rupture 1 % in 10 000 h Rupture 1 % in 100 000 h
Name Number 500°C 600°C 700°C 800°C 900°C 1000°C 500°C 600°C 700°C 800°C 900°C 1000°C 500°C 600°C 700°C 800°C 900°C 1000°C
Ferritic heat resisting steels
X10CrAlSi7 1.4713
X10CrAlSi13 1.4724
X10CrAlSi18 1.4742 +A 160 55 17 7.5 3.6 100 35 9.5 4.3 1.9 55 20 5 2.3 1.0
X10CrAlSi25 1.4762
X18CrN28 1.4749
X3CrAlTi18-2 1.4736
Austenitic heat resisting steels
X8CrNiTi18-10 1.4878 +AT 200 88 30 142 48 15 65 22 10
X15CrNiSi20-12 1.4828 +AT 190 75 35 15 120 36 18 8.5 65 16 7.5 3
X9CrNiSiNCe21-11-2 1.4835 +AT 238 105 50 24 (12) 157 63 27 13 (7) 88 35 15 8 (4)
X12CrNi23-13 1.4833 +AT 190 75 35 15 120 36 18 8.5 65 16 7.5 3
X8CrNi25-21 1.4845 +AT 170 80 35 15 130 40 18 8.5 80 18 7 3
X15CrNiSi25-21 1.4841 +AT 170 90 40 20 5 130 40 20 10 80 18 7 3
X12NiCrSi35-16 1.4864 +AT 180 75 35 15 125 45 20 8 75 25 7 3 1.5
X10NiCrAlTi32-21 1.4876 +AT 200 90 45 20 152 68 30 10 114 48 21 8
X6NiCrNbCe32-27 1.4877 +AT 175 80 24 10 (3.5) 140 52 16 5 (1.5)
X25CrMnNiN25-9-7 1.4872 +AT 80 26 11 45 12 5
X6CrNiSiNCe19-10 1.4818 +AT 238 105 46 18 (7) 157 63 25 10 (4) 88 35 14 5 (1.5)
X6NiCrSiNCe35-25 1.4854 +AT 200 84 41 22 12 127 56 28 15 8 80 36 18 9.2 4.8
X10NiCrSi35-19 1.4786 +AT 190 80 43 22 130 55 26 13
X10NiCrSiNb35-22 1.4887 +AT 190 80 43 22 130 55 26 13
Austenitic-ferritic heat resisting steel
X15CrNiSi25-4 1.4821 +AT 160 55 17 7.5 3.6 100 3.5 9.5 4.3 1.9
Heat resisting nickel alloys
NiCr15Fe-4 2.4816 +A 160 96 38 22 11 297 138 63 29 13 7 215 97 42 17 7
NiCr20Ti 2.4951 +AT 37 20 11 100 36 17 10 6 68 23 11.5 7 5
NiCr22Mo9Nb 2.4956 +A 260 107 34 190 63 20
NiCr23Fe 2.4851 +AT 264 153 60 20 205 101 31 10 5 156 55 17 4 2
NiCr28FeSiCe 2.4889 +AT 40 19 9.5 5.9 28 13 5.9 3

1) Values in parentheses involve time and/or stress extrapolation.